TITLE

Synthesis and spectra of aldehyde- and ketone-O-(2,5-dihydro-2-methoxy-5,5-dimethyl-1,3,4-oxadiazol-2-yl)oximes – Thermal sources of some methoxy(oximino)carbenes

AUTHOR(S)
Klys, Arkadiusz; Dawid, Malgorzata; Warkentin, John
PUB. DATE
May 2005
SOURCE
Canadian Journal of Chemistry;May2005, Vol. 83 Issue 5, p443
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
Ten new oxadiazoline sources of methoxy(oximino)carbenes were synthesized by exchanging the acetoxy group of 2-acetoxy-2-methoxy-Δ3-1,3,4-oxadiazoline with an oximino group. The new compounds were characterized by means of spectroscopy and the formation of carbenes upon thermolysis of a few was demonstrated by means of interception with tert-butyl alcohol. The carbenes fragmented to form methoxycarbonyl and iminyl radicals.
ACCESSION #
17191353

 

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