TITLE

Reactivity of Cyclocarbonate Groups in Modified Epoxy–Amine Compositions

AUTHOR(S)
Garipov, R. M.; Sysoev, V. A.; Mikheev, V. V.; Zagidullin, A. I.; Deberdeev, R. Ya.; Irzhak, V. I.; Berlin, Al. Al.
PUB. DATE
November 2003
SOURCE
Doklady Physical Chemistry;Nov2003, Vol. 393 Issue 1-3, p289
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
Examines the kinetic features of the interaction of cyclocarbonate modifying groups of epoxy compositions with amino groups. Interaction of the alkylene carbonates of the types I , II , XII , and XIII with aliphatic amines; Reaction products includes a urethane group and, in the b position to it, a hydroxy group.
ACCESSION #
16980350

 

Related Articles

  • Synthesis and cyclization of 1-arylalk-1-ene-3,5-diynylamines. Sorokoumov, V.; Morozkina, S.; Balova, I. // Chemistry of Heterocyclic Compounds;May2006, Vol. 42 Issue 5, p615 

    An investigation of the reaction of 1-lithio-1,3-diynes, generated in situ, with nitriles has been carried out. In the case of aromatic nitriles 1-arylalk-1-ene-3,5-diynylamines are formed, which undergo dimerization and cyclization on isolation, giving...

  • Epoxy networks modified by multifunctional polyhedral oligomeric silsesquioxanes (POSS) containing amine groups. dell'Erba, I. E.; Williams, R. J. J. // Journal of Thermal Analysis & Calorimetry;Jul2008, Vol. 93 Issue 1, p95 

    The hydrolytic condensation of a precursor synthesized by the reaction of equimolar amounts of (3-aminopropyl)triethoxysilane and phenylglycidylether led to a distribution of polyhedral oligomeric silsesquioxanes (POSS) containing 8–11 Si atoms, functionalized with amine groups. About 57%...

  • Ammonium decatungstocerate (IV): an efficient catalyst for ring opening of epoxides with aromatic amines. Mirkhani, Valiollah; Tangestaninejad, Shahram; Yadollahi, Bahram; Alipanah, Ladan // Catalysis Letters;Apr2005, Vol. 101 Issue 1/2, p93 

    A mild, convenient and efficient ring opening of oxiranes with aromatic amines was catalyzed by ammonium decatungstocerate (IV) in acetonitrile. The reaction afforded the corresponding products in 92-100% yields. The catalyst was reused for several times with consistent activity.

  • Numbers of faces in disordered patches. Brinkmann, Gunnar; Graver, Jack E.; Justus, Claudia // Journal of Mathematical Chemistry;Feb2009, Vol. 45 Issue 2, p263 

    It has been shown that the boundary structure of patches with all faces of the same size k, all interior vertices of the same degree m and all boundary vertices of degree at most m determines the number of faces of the patch (Brinkmann et al., Graphs and discovery, 2005; Guo et al., Discrete...

  • Solvatochromism of heteroaromatic compounds: XXIX. Configurational isomerism of H complexes of phenols with amides and esters. Oznobikhina, L. P.; Vokin, A. I.; Shulunova, A. M.; Turchaninov, V. K. // Russian Journal of General Chemistry;May2006, Vol. 76 Issue 5, p766 

    Phenol and amides and esters in carbon tetrachloride form an H complex with an OH n bond, whose configurational isomers differ from each other by the direction of the hydrogen bond and, as a result, by the value of the spectral shift. Structural details of such configurational isomers and...

  • Synthesis of 3-amino-4,5-dichloroisothiazole. Potkin, V. I.; Zubenko, Yu. S. // Russian Journal of Organic Chemistry;Apr2009, Vol. 45 Issue 4, p555 

    4,5-Dichloro-1,2-thiazol-3-amine was synthesized starting from accessible 4,5-dichloro-1,2-thiazole-3-carbonyl azide and -3-carboxamide via Curtius and Hofmann rearrangements, respectively. The procedure involving Curtius rearrangement was found to be more advantageous from the preparative...

  • Cadmium chloride-catalyzed regioselective opening of oxiranes with aromatic amines — An improved protocol for the synthesis of 2-amino alcohols. Kumar, S. Ramesh; Leelavathi, P. // Canadian Journal of Chemistry;Jan2007, Vol. 85 Issue 1, p37 

    Epoxides undergo rapid CdCl2-catalyzed ring-opening reaction with aromatic amines in mild reaction conditions (room temperature), affording the corresponding 2-amino alcohols with high regioselectivity.

  • Removal of CO2 and H2S using Aqueous Alkanolamine Solusions. Aliabad, H. Zare; Mirzaei, S. // Proceedings of World Academy of Science: Engineering & Technolog; 

    This work presents a theoretical investigation of the simultaneous absorption of CO2 and H2S into aqueous solutions of MDEA and DEA. In this process the acid components react with the basic alkanolamine solution via an exothermic, reversible reaction in a gas/liquid absorber. The use of amine...

  • A novel feature of intramolecular vibrational redistribution in propargyl alcohol and propargyl amine. Makarov, A. A.; Malinovsky, A. L.; Ryabov, E. A. // Journal of Chemical Physics;9/21/2008, Vol. 129 Issue 11, p116102 

    Intramolecular vibrational redistribution (IVR) from the terminal acetylene mode νHC has been studied for four molecules: H–C=C–CH3 (propyne), H–C=C–CH2Cl (propargyl chloride), H–C=C–CH2OH (propargyl alcohol), and H–C=C–CH2NH2 (propargyl...

Share

Read the Article

Courtesy of AIRBUS FRANCE S.A.S.

Sorry, but this item is not currently available from your library.

Try another library?
Sign out of this library

Other Topics