TITLE

Solubility and Thermodynamics of Solvation of Krypton in Mixtures of H/D Isotopomers of Water and Methanol at 101325 Pa and 278-318 K

AUTHOR(S)
Ivanov, E. V.; Abrosimov, V. K.; Lebedeva, E. Yu.; Ivanova, N. G.
PUB. DATE
May 2003
SOURCE
Russian Journal of General Chemistry;May2003, Vol. 73 Issue 5, p665
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
The solubility of krypton in mixtures of H/D isotopomers of water (H2O, D2O) and methanol (CH3OH, CD3OH, CH3OD) was studied at 101325 Pa and 278.15-318.15 K with a 10 K step. The thermodynamic characteristics of Kr solvation were calculated. The densities of mixtures of water and methanol isotopomers at the examined temperatures were calculated with an error of no more than 1 × 10-5 g cm-3 in the entire composition range. Both in water and aqueous methanol, krypton behaves as a structure-making component, but the alcohol solvation surrounding of the Kr atoms is more labile and more susceptible to the breaking effect of temperature.
ACCESSION #
16694255

 

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