TITLE

Chemical oxidation of fluoroanilines to fluoroazobenzenes and fluorophenazines with potassium ferricyanide and potassium hydroxide

AUTHOR(S)
Leyva, Elisa; Medina, Concepción; Moctezuma, Edgar; Leyva, Socorro
PUB. DATE
December 2004
SOURCE
Canadian Journal of Chemistry;Dec2004, Vol. 82 Issue 12, p1712
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
The oxidation of several fluoroanilines with potassium ferricyanide and potassium hydroxide is described. In this oxidation, the major products are fluoroazobenzenes. In the case of 2-fluoro-substituted anilines, heterocyclic fluorophenazines were obtained in low to moderate yields. The optimal conditions for the reaction and the mechanism are presented.
ACCESSION #
16158376

 

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