TITLE

Measurement of phosphorus segregation in silicon at the atomic scale using scanning tunneling microscopy

AUTHOR(S)
Oberbeck, L.; Curson, N. J.; Hallam, T.; Simmons, M. Y.; Bilger, G.; Clark, R. G.
PUB. DATE
August 2004
SOURCE
Applied Physics Letters;8/23/2004, Vol. 85 Issue 8, p1359
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
In order to fabricate precise atomic-scale devices in silicon using a combination of scanning tunneling microscopy (STM) to position dopant atoms and molecular beam epitaxy to encapsulate the dopants it is necessary to minimize the segregation/diffusion of dopant atoms during silicon encapsulation. We characterize the surface segregation/diffusion of phosphorus atoms from a δ-doped layer in silicon after encapsulation at 250 °C and room temperature using secondary ion mass spectrometry (SIMS) and STM. We show that the surface phosphorus density can be reduced to a few percent of the initial δ-doped density if the phosphorus atoms are encapsulated with 5 monolayers of epitaxial silicon at room temperature. We highlight the limitations of SIMS to determine phosphorus segregation at the atomic scale and the advantage of using STM directly.
ACCESSION #
14154463

 

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