TITLE

Evolution of crystallographic ordering in Hf[sub 1-x]Al[sub x]O[sub y] high-κ dielectric deposited by atomic layer deposition

AUTHOR(S)
Wierner, C.; Fanciulli, M.; Crivelli, B.; Pavia, G.; Alessandri, M.
PUB. DATE
December 2003
SOURCE
Applied Physics Letters;12/22/2003, Vol. 83 Issue 25, p5271
SOURCE TYPE
Academic Journal
DOC. TYPE
Article
ABSTRACT
The evolution of the morphology and of the crystallographic ordering of hafnium aluminates deposited by atomic layer deposition has been investigated. Annealing at temperatures as high as 900 °C in N[sub 2] or O[sub 2] atmosphere is found to promote crystallization of the high-κ layer, together with the growth of an interfacial low-κ oxide. The crystallographic phase has been identified by indexation of transmission electron microscopy selected area diffraction patterns and by Rietveld refinement of grazing incidence x-ray diffractograms. The high κ is found to crystallize in an orthorhombic ternary Hf[sub 1-x]Al[sub x]O[sub 2] phase even for an Al content as high as x=0.74. The temperature of crystallization is higher for the Al-richer alloy. The thickness and the electronic density of the interfacial layer are evaluated by combining cross-sectional transmission electron microscopy and x-ray reflectivity analysis. © 2003 American Institute of Physics.
ACCESSION #
11713192

 

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